γ-graphyne: A promising electron acceptor for organic photovoltaics

Photovoltaics: A Tetraperylene Diimides Based 3D Nonfullerene Acceptor for Efficient Organic Photovoltaics (Adv. Sci. 4/2015)

A Tetraperylene Diimides Based 3D Nonfullerene Acceptor for Efficient Organic Photovoltaics

A nonfullerene acceptor based on a 3D tetraperylene diimide is developed for bulk heterojunction organic photovoltaics. The disruption of perylene diimide planarity with a 3D framework suppresses the self-aggregation of perylene diimide and inhibits excimer formation. From planar monoperylene diimide to 3D tetraperylene diimide, a significant improvement of power conversion efficiency from 0.63...

High voltage hybrid organic photovoltaics using a zinc oxide acceptor and a subphthalocyanine donor.

We demonstrate hybrid organic photovoltaic (HOPV) bilayer devices with very high open circuit voltages (VOC) of 1.18 V based on a sol-gel processed zinc oxide (ZnO) acceptor and a vacuum deposited boron subphthalocyanine chloride (SubPc) donor layer. X-ray photoelectron spectroscopy (XPS) and Kelvin Probe (KP) measurements of the ZnO/SubPc interface show that the ZnO preparation conditions have...

An N-ethylated barbituric acid end-capped bithiophene as an electron-acceptor material in fullerene-free organic photovoltaics.

A new evaporable electron acceptor material for organic photovoltaics based on N-ethyl barbituric acid bithiophene (EBB) has been demonstrated. Bilayer devices fabricated with this non-fullerene acceptor and boron subphthalocyanine chloride (SubPc) donor produce power conversion efficiencies as high as 2.6% with an extremely large open-circuit voltage approaching 1.4 V.

Organic photovoltaics

In the last ten years, the highest efficiency obtained from organic photovoltaics (OPVs), such as bulk heterojunction polymer:fullerene solar cells, has risen from 2.5 to 11 %. This rapid progress suggests that the commercialization of OPVs should be realized soon if we can solve some technical issues. The advances in the development of OPVs can be attributed to four fronts: (i) a better unders...